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‏إظهار الرسائل ذات التسميات petroleum. إظهار كافة الرسائل
‏إظهار الرسائل ذات التسميات petroleum. إظهار كافة الرسائل

الأحد، 10 سبتمبر 2017

Oil drilling Rig

What is Rig?

Owais Khattak at
KCA deutag 72 Location Makori East 6 MOL well
A drilling rig is a machine intend to drill hole in the Earth crust. Drilling rigs are massive structures which are used to drill hole for water, oil or natural gas. For water the rigs can be small, moved easily by one person which are termed as auger. But for oil or natural gas motives it can be very huge structures as you can see in the picture where it seems small but is tall about 46 meters. Drilling rigs can be mounted on trucks usually used for water wells or shallow wells. Small to medium-sized drilling rigs are mobile, such as those used in mineral exploration drilling, blast-hole, water wells and environmental investigations. Larger rigs are capable of drilling through thousands of metres of the Earth's crust, using large "mud pumps" to circulate drilling mud (slurry) through the drill bit and up the casing annulus, for cooling and removing the "cuttings" while a well is drilled. Hoists in the rig can lift hundreds of tons of pipe. Other equipment can force acid or sand into reservoirs to facilitate extraction of the oil or natural gas; and in remote locations there can be permanent living accommodation and catering for crews (which may be more than a hundred). Marine rigs may operate thousands of miles distant from the supply base with infrequent crew rotation or cycle.
As you see the rig in the picture where I stands with it, its a huge structure which is intended to drill deep into the Earth crust. This rig is 2000 horse power and able to drill deep because it can lift huge weight of the drill pipes. 

Rig components

Rig is basically made up of five components without which a rig is incomplete which will be discussed below and the components are
  1. Power
  2. Circulation system
  3. Hoisting system
  4. Rotation 
  5. Blowout preventer (BOP)

Power

A rig is always operated with some energy for the whole of the rig to operate which can be generated through some generators or by placing engines. The rig above was using five generators where three were operational for the rig every time because one cannot stop the rig it costs the operation and two were as backup engines. The power is necessary for a rig or its just a tall standing structure.

Circulation system

Circulation system in terms of rig is mud (slurry) which is made up of mud, water or oil which ever type of mud is required for the subsurface formation, and mixture of chemicals which includes gel, barite for increasing weight, caustic soda, defoamation etc. The mud is pumped from the mud tanks by mud pumps and travels through pipes into drill pipes which goes all the way down into the hole in pipes and gets out through holes in bit and returns to surface via annulus. Annulus is the inner diameter of the hole from which mud comes out to the surface bringing cuttings from the bore hole and creating mud cakes around the hole walls. The mud when comes out of the hole it goes to shakers where mud and well cuttings are separated. The mud also exerts hydrostatic pressure on the formation so that any fluid or gas from formation doesn't enters the bore hole.
Mud cake (1mm) produced in the lab with currently used mud which depicts the inner hole scenario.

Hoisting System

Hoisting system is done by the top drive system (TDS) which is held by strings and pulleys atop. The hoisting system is responsible for lifting the heavy weight of the drill pipes. If you cannot pull out or run in the drill pipes you cannot drill the hole. 

Rotation

Rotation refers to the rotation of drill pipes which in turn rotates the drill bit deep down the hole and cuts the formation. As the drill bit rotates and cuts the formation, if cuttings are not removed from the deep down hole the drill bit can stuck. If not stuck the drill bit will further be crushing the cutting and not the formation this is where the mud works comes in. It lifts up the cutting so that it can drill further and also cools down the bit as friction heats it up and deep the Earth itself is hot.

Blowout preventer (BOP)

BOP is the equipment installed at the surface where drill strings goes in it. The blowout preventer as the name itself is explanatory is used to stop the blowout. The BOP is 1, 2 or 3 stages preventer which is composed or either annulus ram and shear rams, annulus ram, shear rams or upper pipe ram or annulus ram, shear rams, upper pipe ram and lower pipe ram. The BOP is used when the formation pressure exceeds the hydrostatic pressure or else the fluid from the formation will enters the well which is termed as kick. When the kick reaches the surface it will blowout everything within and the rig itself so in order to stop that BOP is installed so that it can stop the pressure from coming out the hole.
BOP

الأحد، 1 مايو 2016

Petroleum system


Petroleum System


In order to understand the petroleum generation and extraction petroleum system should be known
Petroleum system starts with the deposition to storage from where the production is obtained.
Petroleum system journey starts with the deposition of organic matter.

Deposition of organic matter

The deposition of organic matter starts when organism starts to die and deposits deep down the ocean floor and the above deposition of clay (finer grains). The clay particles are about 1/256 mm size and is called shale. Organic matter deposited on the ocean floor cannot be oxidized due to the depth factor so they can produce hydrocarbon. Hydrocarbon generation needs the cooking of organic matter at high temperature and pressure and it is obtained when it goes into overburden of deposition by clay particles and greater depths. 

Source rock

In the petroleum system the source rock are the shale (clay that goes under high pressure and temperature which cooks the organic matter). Sometimes limestone can also be the source rock with 1% of organic matter contains. So theses rocks undergo cooking where the temperature and pressure determines what type of fuel will be generated. Despite of temperature and pressure another factor in producing hydrocarbon is the time span required to generate fuel. The time is a critical factor as if the organic matter is cooked for less time it will not generate hydrocarbon and when it is greater than the oil produce will be converted into gas.

Reservoir rock

Reservoir as indicated by the name reserves of hydrocarbon. the hydrocarbon cannot be obtained from the source rock because of the higher pores but are lesser to none interconnection. For the extraction the pores should be interconnected so that it can travel when are extracted. But if there is no reservoir and obtaining fuel from source rock it must be fractured for permeability generation. Reservoir rock are mostly sandstone which have higher porosity and permeability but in some cases limestone also serves as reservoir rock. Limestone all by self is not a good reservoir due to fine particles present which give less permeability but as limestone is calcium carbonate so it can be dissolved in water which are the Karst topography. Only then can limestone have permeability required for hydrocarbon to be obtained.

Migration

Primary migration

Migration itself is cleared so the primary migration occurs when hydrocarbon moves from source rock to the reservoir rocks. Primary migration occurs when the source rock is fractured due to tectonic forces (plate movements) or by the overburden squeezing the source rock. As HC (hydrocarbon) have low density they moves upward. 

Secondary migration

Secondary migration is the HC movement within the reservoir rocks. The HC will moves upward in the reservoir rocks.

Seal rock

Trap or seal rocks are those that are present above reservoir rocks as HC movement will always be upward. Seal rock are those that have low to none permeability so that HC cannot escape but are trapped within the reservoir rocks. Shale can be seal rock also as they have porosity but do not have permeability factor so HC will be trapped. Types of traps include stratigraphic and structural.
Stratigraphic traps example is shale as a seal rock and structural traps are fold or faults. 

Time period

The last thing in the petroleum system is time as have said it above already, time is required for HC generation which is always critical. No more time and no less time while cooking of the organic matter or it will not produce the fuel.

الجمعة، 25 مارس 2016

Energy Choices, Energy Problems

Energy Choices, Energy Problems 

The Age of Oil and the Oil Crunch 

World energy use, cost and reserves.
Energy usage in industrialized countries grew with dizzying speed through the mid-20th century, and during this time people came to rely increasingly on oil. Eventually, oil supplies within the borders of industrialized countries could no longer match the demand, and these countries began to import more oil than they produced themselves. Through the 1960s, oil prices remained low (about $1.80 a barrel), so this was not a problem. In 1973, however, a complex tangle of politics and war led the Organization of Petroleum Exporting Countries (OPEC) to limit its oil exports. In the United States, fear of an oil shortage turned to panic, and motorists began lining up at gas stations, in many cases waiting for hours to fill their tanks. The price of oil rose to $18 a barrel, and newspaper headlines proclaimed, “Energy Crisis!” Governments in industrialized countries instituted new rules to encourage oil conservation. During the last two decades of the twentieth century, the oil market stabilized. Since 2004, oil prices rose overall, passing the $147/bbl mark in 2008; but the price collapsed in late 2008 when the Great  Recession hit. More recently, the price has hovered around $100/bbl (figure above a). Will a day come when shortages arise not because of politics or limitations on refining capacity, but because there is no more oil to produce? As highly populous countries such as China and India industrialize, the use of fuels accelerates. To understand the issues involved in predicting the future of energy supplies, we must first classify energy resources. As noted earlier, we call a particular resource renewable if nature can replace it within a short time relative to a human life span (in months or, at most, decades). A resource is non-renewable if nature takes a very long time (hundreds to perhaps millions of years) to replenish it. Oil is a non-renewable resource, in that the rate at which humans consume it far exceeds the rate at which nature replenishes it, so we will inevitably run out of oil. The question is, when?
Historians in the future may refer to our time as the Oil Age because so much of our economy depends on oil. How long will the Oil Age last? A reliable answer to this question is hard to come by, because there is not total agreement on the numbers that go into the calculation, especially as the use of unconventional reserves increases, so estimates vary widely. Geologists estimate that we’ve already used a substantial proportion of our conventional reserves, but that there are still about 850 to 1,350 billion barrels of proven conventional oil reserves (figure above b), meaning reserves that have been documented and are still in the ground. Optimistically, there may be an additional 2,000 billion barrels of unproven conventional reserves, meaning oil that has not yet been found but might exist. Thus, the world possibly holds between 850 and 3,350 billion barrels of conventional oil. Presently, humanity guzzles oil at a rate of about 31 billion barrels per year. At this rate, conventional oil supplies will last until some time between 2050 and 2150, not too far in the future. 
Some geologists argue that the beginning of the end of the Oil Age has begun, because the rate of consumption now exceeds the rate of discovery and in many regions, the rate of production has already started to decrease. The peak of production for a given reserve is called Hubbert’s Peak, after the geologist who first emphasized that the production of reserves must decline because oil is a non-renewable resource. Hubbert’s Peak for the United States appears to have been passed in the 1970s. Some researchers argue that the global peak may occur between 2012 and 2014, but this number remains uncertain, and only time will tell. Conservation approaches, such as increasing the gas mileage of cars and increasing the amount of insulation in buildings, could stretch out supplies and make them last decades longer. 
Of course, the picture of oil reserves changes significantly if unconventional reserves are included in estimates. All told, perhaps 1.5 trillion barrels of oil may be trapped in tar sands, and 3 trillion barrels trapped in oil shale. But wide disagreement remains concerning whether it’s fair to include all of these reserves, because a significant proportion would be so difficult and expensive to access that they may never really be an economical energy source.
Even in the most optimistic scenario, including 3,000 billion bbls of conventional oil and perhaps 3,000 billion bbls of accessible unconventional oil, at current rates of consumption, supplies can last for only another 200 years, so the Oil Age will last a total of about 350 years (figure above c). On a timeline representing the 4,000 years since the construction of the Egyptian pyramids, this looks like a very short blip. We may indeed be living during a unique interval of human history.

Can Other Fossil Fuels Replace Oil? 

As true limits to the oil supply approach, societies are looking first at relatively abundant supplies of other conventional fossil fuels, namely natural gas and coal, as sources of energy (figure above d). Rough estimates suggest that world natural gas reserves may exceed 180 trillion cubic meters, which would provide approximately the same amount of energy as 1.2 trillion barrels of oil. But tapping into this gas supply requires expensive technologies for extraction and transport. Similarly, worldwide coal reserves are estimated to be about 850 trillion tons, which contains approximately the same amount of energy as 11 trillion barrels of oil. But the stated number for coal reserves does not distinguish clearly between accessible (mineable) coal and inaccessible coal, which is too deep to mine. And, as is the case for oil, there are political and environmental consequences to relying on gas or coal.

Environmental Issues of Fossil Fuel Use 

Marine oil spills. These can come from drilling rigs, or from tankers.
Environmental concerns about energy resources begin right at the source. Oil drilling requires substantial equipment, the use of which can damage the land. And as demonstrated by the 2010 Gulf of Mexico offshore well blowout, oil drilling can lead to tragic loss of life and disastrous marine oil spills (Offshore Drilling and the Deepwater  Horizon Disaster). Oil spills from pipelines or trucks sink into the subsurface and contaminate groundwater, and oil spills from ships and tankers create slicks that spread over the sea surface and foul the shoreline (figure above a, b). Coal and uranium mining also scar the land and can lead to the production of acid mine runoff, a dilute solution of sulphuric acid that forms when sulphur-bearing minerals such as pyrite (FeS2) in mines react with rainwater. The runoff enters streams and kills fish and plants. Collapse of underground coal mines may cause the ground surface to sink. 
Numerous air-pollution issues also arise from the burning of fossil fuels, which sends soot, carbon monoxide, sulphur dioxide, nitrous oxide, and unburned hydrocarbons into the air. Coal, for example, commonly contains sulphur, primarily in the form of pyrite, which enters the air as sulphur dioxide (SO2) when coal is burned. This gas combines with rainwater to form dilute sulphuric acid (H2SO4), or acid rain. For this reason, many countries now regulate the amount of sulphur that coal can contain when it is burned. But even if pollutants can be decreased, burning fossil fuels still releases carbon dioxide (CO2) into the atmosphere. As we discuss in Chapter 19, CO2 is a greenhouse gas, so a change in the amount of CO2 in the atmosphere can affect climate. Because of concern about CO2 production, research efforts are under way to develop techniques to capture CO2 at power plants, liquefy it, and pump it into reservoir rocks deep underground. This process is called carbon sequestration. 

Offshore Drilling and the Deepwater  Horizon Disaster

The Deepwater Horizon.  
A substantial proportion of the world’s oil reserves reside in the sedimentary basins that underlie the continental shelves of passive continental margins. To access such reserves, oil companies must build offshore drilling platforms. In water less than 600 m (2,000 ft) deep, companies position fixed platforms on towers resting on the sea floor. In deeper water, semi-submersible platforms float on huge submerged pontoons (figure above a). With these, oil companies can now access fields lying beneath 3 km (10,000 ft) of water. 
North America’s largest offshore fields occur in the passive-margin basin that fringes the coast of the Gulf of Mexico. More than 3,500 platforms operate in the Gulf at present, together yielding up to 1.7 million bbl/day. 
During both onshore and offshore exploration, drillers worry about the possibility of a blowout. A blowout happens when the pressure within a hydrocarbon reserve penetrated by a well exceeds the pressure that drillers had planned for, causing the hydrocarbons (oil and/ or gas) to rush up the well in an uncontrolled manner and burst out of the well at the surface in an oil gusher or gas plume. Blowouts are rare because, although fluids below the ground are under great pressure due to the weight of overlying material, engineers fill the hole with drilling mud with a density greater than that of clear water. The weight of drilling mud can counter the pressure of underground hydrocarbons and hold the fluids underground. But if drillers encounter a bed in which pressures are unexpectedly high, or if they remove the mud before the walls of the well have been sealed with a casing (a pipe, cemented in place by concrete) a blowout may happen. 
A catastrophic blowout occurred on April 20, 2010, when drillers on the Deepwater Horizon, a huge semi-submersible platform leased by BP, were finishing a 5.5-km-long (18,000 ft) hole in 1.5-kmdeep (5,000 ft) water south of Louisiana. Due to a series of errors, the casing was not sufficiently strong when workers began to replace the drilling mud with clear water. Thus the high-pressure, gassy oil in the reservoir that the well had punctured rushed up the drillhole. A backup safety device called a blowout preventer failed, so the gassy oil reached the  platform and sprayed 100 m (328 ft) into the sky. Sparks from electronic gear triggered an explosion, and the platform became a fountain of flame and smoke that killed 11 workers. An armada of fireboats could not douse the conflagration (figure above b), and after 36 hours, the still-burning platform tipped over and sank. 
Robot submersibles sent to the sea floor to investigate found that the twisted mess of bent and ruptured pipes at the well head was billowing oil and gas. On the order of 50,000 to 62,000 bbl/day of hydrocarbons entered the Gulf’s water from the well. Stopping this underwater gusher proved to be an immense challenge, and initial efforts to block the well, or to put a containment dome over the well head, failed. It was not until July 15 that the flow was finally stopped, and not until September 19 that a new relief well intersected the blown well and provided a conduit to pump concrete down to block the original well permanently. All told, about 4.2 million bbl of hydrocarbons contaminated the Gulf from the Deepwater Horizon blowout. The spill was devastating to wetlands, wildlife, and the fishing and tourism industries.

Alternative Energy 

Can nuclear power or hydroelectric power replace oil? Vast supplies of uranium, the fuel of traditional nuclear plants, remain untapped. Further, nuclear engineers have designed alternative plants, powered by breeder reactors, that essentially produce new fuel. But many people view nuclear plants with concern because of issues pertaining to radiation, accidents, terrorism, and waste storage, and these concerns have slowed the industry. A substantial increase in hydroelectric power production is not likely, as most major rivers have already been dammed, and industrialized countries have little appetite for taming any more. Similarly, the growth of geothermal-energy output seems limited. 
Because of the potential problems that might result from relying more on coal, hydroelectric, and nuclear energy, researchers have been increasingly exploring clean energy options (see figure 1 d). One possibility is solar power, and the cost of solar power is steadily decreasing. Unfortunately, technologies for large-scale solar energy do not yet exist.  Similarly, we can turn to wind power for relatively small-scale energy production, but covering the landscape with windmills is not appealing, and since wind production varies with wind speed, so it can’t provide a steady supply that the present-day energy grid requires. Fusion power may be possible some day, but physicists and engineers have not yet figured out a way to harness it. 
Clearly, society will be facing difficult choices in the not-so-distant future about where to obtain energy, and we will need to invest in the research required to discover new alternatives. By 2050, 40% of energy may be from renewable sources. In the near term, conservation can play an important role by diminishing demand for fossil fuels. 
Credits: Stephen Marshak (Essentials of Geology)

الثلاثاء، 22 مارس 2016

Oil and Gas

Oil and Gas

What Are Oil and Gas? 

For reasons of economics and convenience, industrialized societies today rely primarily on oil (petroleum) and natural gas for their energy needs. Oil and natural gas, both fossil fuels, consist of hydrocarbons, chain-like or ring-like molecules made of carbon and hydrogen atoms. Chemists consider hydrocarbons to be a type of organic chemical.
Some hydrocarbons are gaseous and invisible, some resemble a watery liquid, some appear syrupy, and some are solid. The viscosity (ability to flow) and the volatility (ability to evaporate) of a hydrocarbon product depend on the size of its molecules. Hydrocarbon products composed of short chains of molecules tend to be less viscous (meaning they can flow more easily) and more volatile (meaning they evaporate more easily) than products composed of long chains, because the long chains tend to tangle up with each other. Thus, short-chain molecules occur in gaseous form (natural gas) at room temperature, moderate-length-chain molecules occur in liquid form (gasoline and oil), and long-chain molecules occur in solid form (tar).

Hydrocarbon Systems 

Oil and gas do not occur in all rocks at all locations. That’s why the goal of controlling oil fields, regions that contain significant amounts of accessible oil underground, has sparked bitter wars. A known supply of oil and gas held underground is a hydrocarbon reserve; if the reserve consists dominantly of oil, it is usually called an oil reserve and if it consists dominantly of gas, it’s a gas reserve. The development of a reserve requires a specific association of materials, conditions, and time. Geologists refer to this association as a hydrocarbon system. We’ll now look at the components of a hydrocarbon system, namely the source rock, the thermal conditions of oil formation, the migratory pathway, and the trap. 

Source Rocks and Hydrocarbon Generation 

News stories often incorrectly imply that oil and gas are derived from buried trees or the carcasses of dinosaurs. In fact, the hydrocarbon molecules of oil and gas are derived from organic chemicals, such as fatty molecules called lipids, that were once in plankton. Plankton is made up of very tiny floating organisms including single-celled and very small multicellular plants (algae) as well as protists and microscopic animals. Typically, most planktonic organisms range in size from 0.02 to 2.0 mm in diameter. When the organisms die, they sink to the floor of the lake or sea that they lived in, and if the water is relatively “quiet” (nonflowing), accumulate.
If the sea-floor or lake-floor environment is rich with oxygen, dead plankton may be eaten or oxidized and transformed into CO2 and CH4 gas, which bubbles away. But in  oxygen-poor waters, the organic material can survive long enough to mix with clay and form an organic-rich, muddy ooze, that can then become buried by still more sediment so that it becomes preserved. Eventually, pressure due to the weight of overlying sediment squeezes out the water, and the ooze becomes compacted and, eventually, lithified to become black, organic shale. (Shale that does not contain organic matter tends to be gray, tan, or red.) Organic shale contains the raw materials from which hydrocarbons form, so we refer to it as a source rock.

The formation of oil. The process begins when organic debris settles with sediment. As burial depth increases, heat and pressure transform the sediment into black shale in which organic matter becomes kerogen. At appropriate temperatures, kerogen becomes oil, which then seeps upward.
If organic shale becomes buried deeply enough (2 to 4 km), it gets warmer, since temperature increases with depth in the Earth. Chemical reactions take place in warm source rocks and slowly transform the organic material in the shale into a mass of waxy molecules called kerogen (figure above). Shale containing 15% to 30% kerogen is called oil shale. If oil shale warms to temperatures of greater than about 90C, kerogen molecules break into smaller oil and natural gas molecules, a process known as hydrocarbon generation. At temperatures over about 160C, any remaining oil breaks down to form natural gas; and at temperatures over 225–250C, organic matter loses all its hydrogen and transforms into graphite (pure carbon). Thus, oil itself forms only in a relatively narrow range of temperatures, called the oil window.

Reservoir Rocks and Hydrocarbon Migration 

The clay flakes that comprise most of an oil shale fit together very tightly and thus prevent kerogen, and any liquid or gaseous hydrocarbons forming within the kerogen, from moving through the rock. Therefore, you can’t simply drill a hole into a source rock and pump out oil the oil won’t flow into the well fast enough to make the process cost efficient. Instead, to obtain oil or gas, companies drill into reservoir rocks, rocks that contain, or could contain, accessible oil or gas, meaning oil or gas that can flow through rock and be sucked into a well fairly easily. 
To be a reservoir rock, a body of rock must have space in which the oil or gas can reside and must have channels through which the oil or gas can move. The space can be in the form of openings, or pores, between clastic grains (which exist because the grains didn't fit together tightly and because cement didn't fill all the spaces during cementation) or in the form of cracks and fractures that developed after the rock formed. In some cases, groundwater passing through rock dissolves minerals to produce new pore space. Porosity refers to the proportion of pore space in a rock. Not all rocks have the same porosity for example, shale has low porosity (10%), whereas poorly cemented sandstone has high porosity (35%). By saying that sandstone has a porosity of 35%, we mean that about a third of a block of the sandstone consists of open space. The oil or gas in a reservoir rock occurs in the pores, and thus is distributed through the rock it does not occur in open pools underground. Permeability refers to the degree to which pore spaces are connected to one another. In a rock with high permeability, there are many tiny channel ways linking pores, and/or many interconnected cracks cutting through the rock, so that fluids are not trapped in pores but rather can flow  through the rock. The greater the porosity, the greater the capacity of a reservoir rock to hold oil; and the greater the rock’s permeability, the easier it is for the oil to be extracted. 

Initially, oil resides in the source rock. Because it is buoyant relative to groundwater, the oil migrates into the overlying reservoir rock. The oil accumulates beneath a seal rock in a trap.
To fill the pores of a reservoir rock, oil and gas must first migrate (move) from the source rock into a reservoir rock, a process that can take thousands to millions of years to happen (figure above). Why do hydrocarbons migrate? Oil and gas are less dense than water, so they try to rise toward the Earth’s surface to get above groundwater, just as salad oil rises above the vinegar in a bottle of salad dressing. Natural gas, being less dense, ends up rising above oil. In other words, buoyancy drives oil and gas upward. Typically, a hydrocarbon system must have a good migration pathway, such as a set of permeable fractures, in order for large volumes of hydrocarbons to move.

Traps and Seals 

If oil or gas escapes from the reservoir rock and ultimately reaches the Earth’s surface, where it leaks away at an oil seep, there will be none left underground to extract. Thus, for an oil reserve to exist, oil and gas must be held underground in the reservoir rock by means of a geologic configuration called a trap.
There are two components to an oil or gas trap. First, a seal rock, a relatively impermeable rock such as shale, salt, or unfractured limestone, must lie above the reservoir rock and stop the hydrocarbons from rising further. Second, the seal and reservoir rock bodies must be arranged in a geometry that localizes the hydrocarbons in a restricted area. Geologists recognize several types of hydrocarbon trap geometries, four of which are described below.

Types of Oil and Gas Traps

Geologists who work for oil companies spend much of their time trying to identify underground traps. No two traps are exactly alike, but we can classify most into the following four categories.

Examples of oil traps.  A trap is a configuration of a seal rock over a reservoir rock, in a geometry that keeps the oil underground.
  • Anticline trap: In some places, sedimentary beds are not horizontal, as they are when originally deposited, but have been bent by the forces involved in mountain building. These bends, as we have seen, are called folds. An anticline is a type of fold with an arch-like shape (figure above a). If the layers in the anticline include a source rock overlain in turn by a reservoir rock that is overlain by a seal rock, then we have the recipe for an oil reserve. The oil and gas rise from the source rock, enter the reservoir rock, and rise to the crest of the anticline, where they are trapped by a seal.
  • Fault trap: A fault is a fracture on which there has been sliding. If the slip on the fault crushes and grinds the adjacent rock to make an impermeable layer along the fault, then oil and gas may migrate upward along bedding in the reservoir rock until they stop at the fault surface (figure above b). Alternatively, a fault trap develops if the slip on the fault juxtaposes an impermeable rock layer against the reservoir rock. 
  • Salt-dome trap: In some sedimentary basins, the sequence of strata contains a thick layer of salt, deposited when the basin was first formed and seawater covering the basin was shallow and very salty. Sandstone, shale, and limestone overlie the salt. The salt layer is not as dense as sandstone or shale, so it is buoyant and tends to rise up slowly through the overlying strata. Once the salt starts to rise, the weight of surrounding strata squeezes the salt out of the layer and up into a growing, bulbous salt dome. As the dome rises, it bends up the adjacent layers of sedimentary rock. Oil and gas in reservoir rock layers migrate upward until they are trapped against the boundary of the salt dome, for salt is not permeable (figure above c). 
  • Stratigraphic trap: In a stratigraphic trap, a tilted reservoir rock bed “pinches out” (thins and disappears) up its dip between two impermeable layers. Oil and gas migrating upward along the bed accumulate at the pinchout (figure above d).
Credits: Stephen Marshak (Essentials of Geology)

الخميس، 8 أكتوبر 2015

Unconventional reserves of Hydrocarbons

Unconventional reserves of Hydrocarbons

Oil that can be extracted from reserves in the porous and permeable reservoir rocks of oil traps. Such reserves have come to be known as conventional reserves, because accessing them uses technology that has been around for years. In the past 10 to 15 years, energy companies have begun to increase their focus on extracting hydrocarbons from unconventional reserves, meaning reserves that had previously been left in the ground or disposed of because they cannot be tapped without using new technologies. Let’s look at a few examples of these reserves. 

Natural Gas 

Natural gas consists of volatile, short-chain hydrocarbon molecules (methane, ethane, propane, and butane). Gas burns more cleanly than oil, in that combustion of gas produces only CO2 and water, while the burning of oil not only produces CO2 and water, but also complex organic pollutants. Thus, natural gas has become the preferred fuel for home cooking and heating, and in some localities, for electricity production. It can also be used to run cars and trucks, if the vehicles have been appropriately modified. Natural gas has not yet been used as widely as other hydrocarbons, because gas transportation, which requires high-pressure pipelines or special ships, is quite expensive. But its use is increasing rapidly. As we have seen, gas often occurs in association with oil. Unfortunately, at many oil wells, it is not economical to capture and transport the gas, so this gas vents from a pipe and is burned in a flare where it enters the air. (In localities where rock has been heated to temperatures higher than the oil window, reservoir rock may contain only gas and there may be enough to be worth pumping and capturing by conventional means.) Recently, the use of directional drilling and hydraulic fracturing has made it possible to extract large quantities of gas directly from source rocks. Large reserves of such shale gas underlie states in the northeastern United States, and are currently being drilled to provide energy for east-coast cities (Box 12.2). Intense exploration for shale gas reserves has begun worldwide.

Tar Sands (Oil Sands) 


So far, we’ve focused our discussion on hydrocarbon reserves that can be pumped from the subsurface in the form of a liquid or gas. But in several locations around the world, most notably Alberta (in western Canada) and Venezuela, vast reserves of very viscous, tar-like “heavy oil” exist. This heavy oil, known also as bitumen, has the consistency of gooey molasses, and thus cannot be pumped directly from the ground. It fills the pore spaces of sand or of poorly cemented sandstone, constituting up to 12% of the sediment or rock volume. Sand or sandstone containing such high concentrations of bitumen is known as tar sand or oil sand. Production of usable oil from tar sand is difficult and expensive, but not impossible. It takes about 2 tons of tar sand to produce one barrel of oil. Oil companies mine near-surface deposits in vast open-pit mines and then heat the tar sand in a furnace to extract the oil. Producers then crack the heavy oil molecules to produce smaller, more usable molecules. Trucks dump the drained sand back into the mine pit. To extract oil from deeper deposits of tar sand, oil companies drill wells and pump steam or solvents down into the sand to liquefy the oil enough so that it can be pumped out. 

Oil Shale 


Vast reserves of organic shale have not been subjected to temperatures of the oil window, or if they were, they did not stay within the oil window long enough to complete the transformation to oil. Such rock still contains a high proportion of kerogen. Shale that contains at least 15% to 30% kerogen is called oil shale. Lumps of oil shale can be burned directly and thus have been used as a fuel since ancient times. In general, however, energy companies produce liquid oil from oil shale. The process involves heating the oil shale to a temperature of 500nC; at this temperature, the shale decomposes and the kerogen transforms into liquid hydrocarbon and gas. As is the case with tar sand, production of oil from oil shale is possible, but very expensive.

الثلاثاء، 6 أكتوبر 2015

Oil Exploration and Production

Oil Exploration and Production

Birth of the Oil Industry 

In the United States, during the first half of the 19th century, people collected “rock oil” (later called petroleum, from the Latin words petra, meaning rock, and oleum, meaning oil) at seeps and used it to grease wagon axles and to make patent medicines. But such oil was rare and expensive. In 1854, George Bissel, a New York lawyer, came to the realization that oil might have broader uses, particularly as fuel for lamps, to replace increasingly scarce whale oil. Bissel and a group of investors contracted Edwin Drake, a colourful character who had drifted among many professions, to find a way to drill for oil in rocks beneath a hill near Titusville, Pennsylvania, where oily films floated on the water of springs. Using the phony title “Colonel” to add respectability, Drake hired drillers and obtained a steam-powered drill. Work was slow and the investors became discouraged, but the very day that a letter arrived ordering Drake to stop drilling, his drillers found that the hole, which had reached a depth of 21.2 m, had filled with oil. They set up a pump, and on August 27, 1859, for the first time in history, pumped oil out of the ground. No one had given much thought to the question of how to store the oil, so workers dumped it into empty whisky barrels. This first oil well yielded 10 to 35 barrels a day, which sold for about $20 a barrel (1 barrel equals 42 gallons). Within a few years, thousands of oil wells had been drilled in many states, and by the turn of the 20th century, civilization had begun its addiction to oil. Initially, most oil went into the production of kerosene for lamps. Later, when electricity took over from kerosene as the primary source for illumination, gasoline derived from oil became the fuel of choice for the newly invented automobile. Oil was also used to fuel electric power plants. In its early years, the oil industry was in perpetual chaos. When “wildcatters” discovered a new oil field, there would be a short-lived boom during which the price of oil could drop to pennies a barrel. In the midst of this chaos, John D. Rockefeller established the Standard Oil Company, which monopolized the production, transport, and marketing of oil. In 1911, the Supreme Court broke down Standard Oil into several companies including Exxon (Esso), Chevron, Mobil, Sohio, Amoco, Arco, Conoco, and Marathon some of which have recombined in recent decades. Oil became a global industry governed by the complex interplay of politics, profits, supply, and demand. 

The Modern Search for Oil 


Wildcatters discovered the earliest oil fields either by blind luck or by searching for surface seeps. But in the 20th century, when most known seeps had been drilled and blind luck became too risky, oil companies realized that finding new oil fields would require systematic exploration. The modern-day search for oil is a complex, sometimes dangerous, and often exciting procedure with many steps. Source rocks are always sedimentary, as are most reservoir and seal rocks, so geologists begin their exploration by looking for a region containing appropriate sedimentary rocks. Then they compile a geologic map of the area, showing the distribution of rock units. From this information, it may be possible to construct a preliminary cross section depicting the geometry of the sedimentary layers underground as they would appear on an imaginary vertical slice through the Earth.

To add detail to the cross section, an exploration company makes a seismic-reflection profile of the region. To obtain a seismic profile, a special vibrating truck or a dynamite explosion sends seismic waves (shock waves that move through the Earth) into the ground. The seismic waves reflect off contacts between rock layers, just as sonar waves sent out by a submarine reflect off the bottom of the sea. Reflected seismic waves then return to the ground surface, where sensitive instruments (geophones) record their arrival. A computer measures the time between the generation of a seismic wave and its return, and from this information defines the depth to the contacts at which the wave reflected. With such information, the computer constructs an image of the configuration of underground rock layers and, in some cases, can “see” reserves of oil or gas. 

Drilling and Refining 


If geological studies identify a trap, and if the geologic history of the region indicates the presence of good source rocks and reservoir rocks, geologists make a recommendation to drill. (They do not make such recommendations lightly, as drilling a deep well may cost over $50 million.) Once the decision has been made, drillers go to work. These days, drillers use rotary drills to grind a hole down through rock. A rotary drill consists of a pipe tipped by a rotating bit, which is a bulb of metal studded with hard metal prongs. As the bit rotates, it scratches and gouges the rock, turning it into powder and chips. Drillers pump “drilling mud,” a slurry of water mixed with clay and other materials, down the center of the pipe. The mud flows down, past a propeller that rotates the drill bit, and then squirts out of holes at the end of the bit. The extruded mud cools the bit head, which otherwise would heat up due to friction as it grinds against rock, then flows up the hole on the outside of the drill pipe. As it rises, the mud carries “rock cuttings” (fragments of rock that had been broken up by the drill bit) up and out of the hole. Mud also serves another very important purpose its weight counters the pressure of the oil and gas in underground reservoir rocks. By doing so, it prevents hydrocarbons from entering the hole until drilling has been completed, the hole has been “finished” (by removing the drill pipe and sealing the walls of the drill hole with concrete), and the hole has been capped. Were it not for the mud, the natural pressure in the reservoir rock would drive oil and/or gas into the hole. And if the pressure were great enough, the hydrocarbons would rush up the hole and spurt out of the ground as a gusher or blowout. Gushers and blowouts can be disastrous, because they spill oil onto the land and, in some cases, ignite into an inferno. Early drilling methods could produce only vertical drill holes. But as technology advanced, drillers developed methods to control the path of the drill bit so the hole can curve and become diagonal or even horizontal. Such directional drilling has become so precise that a driller, using a joystick to steer the bit, and sensors that specify the exact location of the bit in 3-D space, can hit an underground target that is only 15 cm wide from a distance of a few kilometres. Drillers use derricks (towers) to hoist the heavy drill pipe. To drill in an offshore hydrocarbon reserve, one that occurs in strata beneath the continental shelf, the derrick must be constructed on an offshore-drilling facility. These may be built on huge towers rising from the sea floor, or on giant submerged pontoons. Using directional drilling, it’s possible to reach multiple targets from the same platform. On completion of a hole, workers remove the drilling rig and set up a pump. Some pumps resemble a bird pecking for grain; their heads move up and down to pull up oil that has seeped out of pores in the reservoir rock into the drill hole. You may be surprised to learn that simple pumping gets only about 30% of the oil in a reservoir rock out of the ground. Thus oil companies may use secondary recovery techniques to coax out more oil (as much as 20% more). For example, a company may drive oil toward a drill hole by forcing steam into the ground nearby. The steam heats the oil in the ground, making it less viscous, and pushes it along. In some cases, drillers create artificial fractures in rock around the hole by pumping a high-pressure mixture of water, various chemicals, and sand into a portion of the hole. This process, called hydrofracturing (or “fracking”) creates new fractures and opens up pre-existing ones. The sand left by the fracturing fluid keeps the cracks from closing tightly, so they remain permeable. The fractures provide easy routes for the oil to follow from the rock to the well. Once extracted directly from the ground, “crude oil” flows first into storage tanks and then into a pipeline or tanker, which transports it to a refinery. At a refinery, workers distil crude oil into several separate components by heating it gently in a vertical pipe called a distillation column. Lighter molecules rise to the top of the column, while heavier molecules stay at the bottom. The heat may also “crack” larger molecules to make smaller ones. Chemical factories buy the largest molecules left at the bottom and transform them into plastics.

Where Does Oil Occur? 

Reserves are not randomly distributed around the Earth. Currently, countries bordering the Persian Gulf contain the world’s largest reserves in 25 supergiant fields. In fact, this region has almost 60% of the world’s reserves. Reserves are specified in barrels (bbl); 1 bbl 42 gallons 159 liters. Why is there so much oil in the Middle East? Much of the region that is now the Middle East was situated in tropical areas between latitude 20n south and 20n north between the Jurassic (135 Ma) and the Late Cretaceous (65 Ma). Biological productivity was very high in these tropical regions, so the muds that accumulated there were very organic rich and lithified to become excellent source rocks. Thick layers of sand buried the source rocks and eventually became porous sandstones that make excellent reservoir rocks. Later, mountain-building processes folded the layers into large anticlines, which are excellent traps. The Middle East is not the only source of oil. Reserves also occur in sedimentary basins formed along passive continental margins, such as the Gulf Coast of the United States and the Atlantic Coasts of Africa and Brazil, as well as in intracratonic and foreland basins within continents.

الخميس، 20 أغسطس 2015

Oil Well Drilling Process with animation


الخميس، 6 أغسطس 2015

Is There Oil Beneath My Property?



Is There Oil Beneath My Property? First Check the Geological Structure

Accumulations of crude oil and gas require a source rock, which is an organic-rich sedimentary rock that produces petroleum as the organisms decompose following burial. Petroleum migrates from the source rock until it encounters impermeable rock or the earth's surface, where it is lost in seeps. Porous and permeable reservoir rocks allow petroleum to accumulate below impermeable layers. Geologic structures provide traps to further concentrate the accumulating petroleum. Anticlines are the best traps and the first recognized by geologists searching for oil. These structures can form "oil pools" with stacked levels of water (lowest), oil and natural gas (highest) against the impermeable rock above the reservoir.



Other types of traps have been recognized including faults, unconformities, and facies changes. Modern petroleum exploration is sophisticated, but there is no way short of drilling to determine the presence of oil. "Wildcat" wells only have a 1 in 10 chance of discovery, which explains why future oil supplies will be more difficult and costly to find.........
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Oil Trap

A set of conditions that hold petroleum in a reservoir rock and prevents its escape by migration.

Major types of Petroleum Traps.  In all cases, impermeable rock encloses or caps the petroleum.


الخميس، 30 يوليو 2015

Accumulation of organic matter


It is well documented that oil accumulations are of organic origin and formed from organic matter in sediments. Methane can be formed inorganically and is found in the atmosphere of several other planets, but inorganic methane from the interior of the earth is likely to be well dispersed and thus not form major gas accumulations in the earth’s crust. The organic matter from which petroleum is derived originated through photosynthesis, i.e. storage of solar energy. Sunlight is continuously transformed into such energy on Earth but only a very small proportion of the solar energy is preserved as organic matter and petroleum. The oil and gas which forms in sedimentary basins each year is thus minute in comparison with the rate of exploitation (production) and consumption. In practice petroleum must therefore be regarded as a non-renewable resource even though some petroleum is being formed all the time. Most of the organic materials which occur in source rocks for petroleum are algae, formed by photosynthesis.The zoo plankton and higher organisms that are also represented grazed the algae and were thus indirectly dependent on photosynthesis too. The energy which we release when burning petroleum is therefore stored solar energy. Since petroleum is derived from organic matter, it is important to understand how and where sediments with a high content of organic matter are deposited. The total production of organic material in the world’s oceans is now 5×1010 tonnes/year. Nutrients for this organic production are supplied by erosion of rocks on land and transported into the ocean. The supply of nutrients is therefore greatest in coastal areas, particularly where sediment-laden rivers discharge into the sea. Plant debris is also supplied directly from the land in coastal areas. Biological production is greatest in the uppermost 20–30 m of the ocean and most of the phytoplankton growth takes place in this zone. In clear water, sunlight penetrates much deeper than in turbid water, but in clear water there is usually little nutrient supply. At about 100–150 m depth, sunlight is too weak for photosynthesis even in very clear water. Phytoplankton provides nutrition for all other marine life in the oceans. Zooplankton feed on phytoplankton and therefore proliferate only where there is vigorous phytoplankton production. Organisms sink after they have died, and may decay so that nutrients are released and recycled at greater depths. Basins with restricted water circulation will preserve more organic matter and produce good source rocks which may mature to generate oil and gas. In polar regions, cold dense water sinks to great depths and flows along the bottom of the deep oceans towards lower latitudes. This is the thermal conveyor belt transporting heat to higher latitudes and it keeps the deep ocean water oxidizing. In areas near the equator where the prevailing winds are from the east the surface water is driven away from the western coast of the continents. This generates a strong up welling of nutrient-rich water from the bottom of the sea which sustains especially high levels of primary organic production. The best examples of this are the coast of Chile and off West Africa. Through photosynthesis, low energy carbon dioxide and water are transformed into high energy carbohydrates (e.g. glucose):

CO2 + H2O → CH2O (organic matter) + O2

The production of organic matter is not limited by carbon dioxide or water, but by nutrient availability. 
Phosphorus (P) and nitrogen (N) are the most important nutrients, though the supply of iron can also be limiting for alga production. It is this process of photosynthesis, which started 4 billion years ago, that has built up an atmosphere rich in oxygen while accumulating reduced carbon in sedimentary rocks as oil, gas and coal. Most of the carbon is nevertheless finely divided within sedimentary rocks, for example shales and limestones, in concentrations too low to generate significant oil and gas. Energy stored by photosynthesis can be used directly by organisms for respiration. This is the opposite process, breaking carbohydrates down into carbon dioxide and water again, so that the organisms gain energy. This occurs in organisms at night when there is no light to drive photosynthesis. Also when we burn hydrocarbons, e.g. while driving a car, energy is obtained by oxidation, again essentially reversing the photosynthesis equation quoted above. Oxidation of 100 g glucose releases 375 kcal of energy. Carbohydrates that are produced but not consumed by respiration can be stored as glucose, cellulose or starch in the cell walls. Photosynthesis is also the biochemical source for the synthesis of lipids and proteins. Proteins are large, complex molecules built up of condensed amino acids (e.g. glycine (H2NCH2−COOH)). 
Dried phytoplankton contains 45–55% carbon, 4.5–9% nitrogen, 0.6–3.3% phosphorus and up to 25% of both silica and carbonate. Planktonic algae are the main contributors to the organic matter which gives rise to petroleum. Among the most important are diatoms, which have amorphous silica (opal A) shells.
Diatoms are most abundant in the higher latitudes and are also found in brackish and fresh water. Blue - green algae (cyanobacteria) which live on the bottom in shallow areas, also contribute to the organic material in sediments. In coastal swamps, and particularly on deltas, we have extensive production of organic matter in the form of plants and trees which may avoid being oxidised by sinking into mud or bog. The residues of these higher land plants may form peat, which with deeper burial may be converted into lignite and bituminous coal. But such deposits are also a potential source of gas and oil. Plant matter, including wood, also floats down rivers and is deposited when it sinks to the bottom, usually in a near shore deltaic environment. When the trees rot they release CO2 and consume as much oxygen as the plant produced during the whole period when it was growing. There is thus no net contribution of oxygen to the atmosphere. This also applies to the bulk of the tropical rainforests. Where trees and plants sink into black mud, preventing them from being oxidised, there is a net contribution of oxygen to the atmosphere and a corresponding reduction of CO2 in the atmosphere. All animal plankton (zooplankton) live on plant plankton, and in turn are eaten by higher organisms in the food chain. At each step in the food chain, which we call a trophic level, the amount of organic matter (the biomass) is reduced to 10%. Ninety percent of the production of organic matter is therefore from algae. This is why algae and to some extent zooplankton account for the bulk of the organic material which can be transformed into oil. Larger animals such as dinosaurs are totally irrelevant as sources of oil. The most important of the zooplankton which provide organic matter for petroleum are:
Radiolaria
Foraminifera
Pteropods
  1. Radiolaria – silica shells, wide distribution, particularly in tropical waters. 
  2. Foraminifera – shells of calcium carbonate. 
  3. Pteropods – pelagic gastropods (snails) with a foot which has been converted into wing-shaped lobes; carbonate shells.
This is the second lowest level within the marine food chain. These zooplanktonic organisms are eaten by crustaceans which themselves are eaten by fish. The total amount of organic matter that can be produced in the ocean is dependent on the nutrient supply from rivers, but river water does not only carry inorganic nutrients. It also contains significant amounts of organic matter, in particular humic acid compounds, lignin and similar substances formed by the breakdown of plant material which are weakly soluble in cold water. When the river water enters the sea, there is precipitation due to the increased pH and lower surface temperature in the ocean. Other plant materials, like waxes and resins, are more chemically resistant to breakdown and are insoluble in water. Such organic particles tend to attach themselves to mineral grains and accompany sediment out into the ocean. Most of the oil reservoirs which have been formed since the Palaeozoic have been uplifted and eroded, and over time vast quantities of oil have flowed (seeped) out onto the land or into the sea. In this sense, oil pollution is a natural process. Only a small proportion of the petroleum that has been formed in source rocks has actually become trapped in a reservoir. One might expect this seepage to have provided a source of recycled petroleum in younger sediments, but petroleum breaks down extremely rapidly when subjected to weathering, oxidising to CO2, and the nutrients (P, N) that were required to form the organic matter are released and may act like a fertilizer. On land, evaporation will remove the lighter components while bacteria will degrade the heavier components. Fossil asphalt lakes consist of heavy substances which neither evaporate nor can be easily broken down by bacteria. In the ocean, the lighter components will dissolve quite rapidly, while the heavier asphalt fraction will sink to the bottom and be degraded and recycled. In uplifted sedimentary basins like the Ventura Basin and the Los Angeles Basin in Southern California there are abundant natural oils seeps both onshore and offshore. On the beaches from Santa Barbara towards Los Angeles there are many natural oil seeps.

الأربعاء، 29 يوليو 2015

Formation of coal, oil and gas


The branch of geology that has the greatest economic importance worldwide is the study of fossil fuels (coal, oil and natural gas): they form by diagenetic processes that alter material made up of the remains of organisms. The places where the original organic material forms can be understood by studying depositional processes, but the formation of coal from plant material and the migration of volatile hydrocarbons as oil and gas require an understanding of the diagenetic history of the sedimentary rocks where they are found.

Coal-forming environments


Vegetation on the land surface is usually broken down either by grazing animals or by microbial activity. Preservation of the plant material is only likely if the availability of oxygen is restricted, as this will slow down microbial decomposition and allow the formation of peat, which is material produced by the decay of land vegetation. In areas of standing or slowly flowing water conditions can become anaerobic if the oxygen dissolved in the water is used up as part of the decay process. These waterlogged areas of accumulation of organic material are called mires, and are the principal sites for the formation of thick layers of peat. Mires can be divided into two types: areas where most of the input of water is from rainfall are known as ombotrophic mires or bogs; places where there is a through-flow of groundwater are called rheotrophic mires or swamps. In addition there are also rheotrophic mires that have an input of clastic sediment, and these are referred to as marshes, or salt marshes if the water input is saline.

The significance of these different settings for peat formation is that these environmental factors have a strong influence on the quality and economic potential of a coal that might subsequently be formed. Bogs tend to have little clastic input, so the peat (and hence coal) is almost pure plant material: the peat can be many metres thick, but is usually of limited lateral extent. Swamp environments can be more extensive, but the through-flowing water may bring in clay, silt and sand particles that make the coal impure (it will have a high ash content). Also, if the water is saline, it will contain sulphates and these lead to the formation of sulphides (typically iron pyrite) in the coal and give the deposit a high sulphur content: this is not desirable because it results in sulphur dioxide emissions when the coal is burnt. The ash and sulphur content are the two factors that are considered when assessing the coal grade, as the lower they are, the higher the grade. A wet environment is required to form a mire and therefore a peat, so environments of their formation tend to be concentrated in the wetter climatic belts around the Equator and in temperate, higher latitudes. In warmer climates plant productivity is greater, but the microbial activity that breaks down tissue is also more efficient. Both plant growth and microbial breakdown processes are slower in cooler environments, but nevertheless the fastest rates of peat accumulation (over 2mm yr 1) are from tropical environments and are ten times the rate of peat accumulation in cooler climes. Coals that originate as peat deposits are known as humic coals, but not all coals have this origin. Sapropelic coals are deposits of aquatic algae that accumulate in the bottoms of lakes and although they are less common, they are significant because they can be source rocks for oil: humic coals do not yield oil, but can be the origins of natural gas.

Formation of coal from peat

The first stage of peat formation is the aerobic, biochemical breakdown of plant tissue at the surface that produces a brownish mass of material. This initially formed peat is used as a fuel in places, but has a low calorific value. The calorific value is increased as the peat is buried under hundreds of metres of other sediment and subjected to an increase in temperature and pressure. Temperature is in fact the more important factor, and as this increases with depth (the geothermal gradient) the peat goes through a series of changes. Volatile compounds such as carbon dioxide and methane are expelled, and the water content is also reduced as the peat goes through a series of geochemical changes. As oxygen, hydrogen and nitrogen are lost, the proportion of carbon present increases from 60% to over 90%, and hence the calorific value of the coal increases. Differences in the degree to which the original peat has been coalified are described in terms of coal rank. Transitional between peat and true coal is lignite or brown coal, which is exploited as an energy source in places. Going on through the series, low-rank coal is referred to as sub-bituminous coal, middle rank is bituminous and the highest rank coals are known as anthracite. In the process of these reactions, the original layer of peat is reduced considerably in thickness and a bed of bituminous coal may be only a tenth of the thickness of the original layer of peat.

Formation of oil and gas


Naturally occurring oil and gas are principally made up of hydrocarbons, compounds of carbon and hydrogen: petroleum is an alternative collective term for these materials. The hydrocarbon compounds originate from organic matter that has accumulated within sedimentary rocks and are transformed into petroleum by the processes of hydrocarbon maturation. This takes place in a series of stages dependent upon both temperature and time. The first stage is biochemical degradation of proteins and carbohydrates in organic matter by processes such as bacterial oxidation and fermentation. This eogenesis eliminates oxygen from kerogen, the solid part of the organic matter that is insoluble in organic solvents. 
Three main types of kerogen are recognised: 
  • Type I is derived from planktonic algae and amorphous organic material and is the most important in terms of generating oil.
  • Type II consists of mixed marine and continental organic material (algae, spores, cuticles) which forms gas and waxy oils.
  • Type III originates from terrestrial woody matter and is a source of gas only. 
Eogenesis occurs at temperatures of up to 408 C and at up to depths of just over 1000 m. At burial depths of between about 1000 and 4000 m and at temperatures of between 408 C and 1508 C, the phase of diagenesis known as catagenesis further transforms the kerogen. This stage of thermal maturation is also known as the ‘oil window’ because liquid petroleum forms from Type I kerogen under these conditions. With increasing temperature the proportion of gas generated increases. Generation of oil by organic maturation of kerogen is a process that requires millions of years, during which time the strata containing the organic matter must remain within the oil window of depth and temperature. At higher temperatures and burial depths only methane is produced from all kerogen types, a stage known as metagenesis. Formation of oil, which is made up of relatively long-chain hydrocarbons that are liquid at surface temperatures, from sedimentary organic matter requires a particular set of conditions. First, the organic matter must include the remains of planktonic algae that will form Type I kerogen: this material normally accumulates in anaerobic conditions in anoxic marine environments and in lakes. Second, the organic material must be buried in order that catagenesis can generate liquid hydrocarbons within the correct temperature window: if buried too far too quickly only methane gas will be formed. The third factor is time, because the kerogen source rock has to lie within the oil window for millions of years to generate significant quantities of petroleum. Gas consisting of short-chain hydrocarbons, principally methane, is formed from Type III kerogen and at higher maturation temperatures. Burial of coal also generates natural gas (principally methane) and no oil. The methane generated from coal may become stored in fractures in the coal seam as coal bed methane, which is a hazard in underground coal mining, but can also be exploited economically.


Oil and gas reservoirs

The hydrocarbons generated from kerogen are compounds that have a lower density than the formation water present in most sedimentary successions. They are also immiscible with water and droplets of oil or bubbles of gas tend to move upwards through the pile of sedimentary rocks due to their buoyancy. This hydrocarbon migration proceeds through any permeable rock until the oil or gas reaches an impermeable barrier.

Hydrocarbon traps

Oil and gas become trapped in the subsurface where there is a barrier formed by impermeable rocks, such as well-cemented lithologies, mudrock and evaporite beds. These impermeable lithologies are known as cap rocks. The hydrocarbons will find their way around the cap-rock barrier unless there is some form of hydrocarbon trap that prevents further upward migration. Structural traps are formed by folds, such as anticlines, especially if they are domeshaped in three dimensions, and by faults that seal a porous reservoir rock against an impermeable unit. Other traps are stratigraphic traps, formed beneath unconformities and in places where the reservoir rock pinches out laterally: porous rocks such as limestone reefs that pass laterally into finer grained deposits and where sand bodies are laterally limited and enclosed by mudrocks are examples of stratigraphic traps. The size and shape of the trap determines the volume of oil and/or gas that is contained by the structure, and hence is an important factor in assessing the economics of a potential oil field. In the absence of traps and caps the hydrocarbon reaches the surface and leaks to the atmosphere. Partial release of hydrocarbons from the subsurface as oil seeps and gas seeps can be important indicators of the presence of hydrocarbons.

Reservoir rocks

Almost all oil and gas accumulations occur underground within the pore spaces of beds of sedimentary rocks. In a few rare cases there are accumulations of hydrocarbons in subterranean caverns formed by dissolution of limestone, but the vast majority of reserves are known hosted between grains in sandstones or within the structures of limestones. For a sedimentary rock to be a suitable reservoir unit, it must be both porous and permeable. Porosity is presented as a percentage of the rock volume. Permeability is expressed in darcy units, with a value of 1 darcy representing a very good permeability for a hydrocarbon reservoir. Some of the best reservoir facies are beds of wellsorted sands deposited in sandy deserts and shallow seas, because these contain a high primary porosity. For similar reasons oolitic grainstones can be good reservoirs, and boundstones formed in reefs have a lot of void spaces within the original structure. There are examples of hydrocarbon reservoirs in deposits of many other environments, including rivers, deltas and submarine fans. Limestones may also have important secondary porosity due to dissolution and diagenetic changes. The reservoir quality of a rock is reduced by two main factors. First, the presence of mud reduces both porosity and permeability because clay minerals fill the spaces between grains and block the throats between them. Second, cementation reduces porosity and permeability by crystallising
minerals in the pore spaces, sometimes to the extent of reducing the porosity to zero.

Economic oil and gas accumulations


Exploration for economic reserves of hydrocarbons requires knowledge of the depositional history of an area to determine whether suitable source rocks are likely to have formed and if there are any suitable reservoir and cap lithologies in the overlying succession. This analysis of the sedimentology is an essential part of oil and gas exploration. Knowledge of postdepositional events is also important to provide an assessment of the thermal and burial history that controls the generation of hydrocarbons.

الخميس، 16 يوليو 2015

Heavy oil and Tar sands

Heavy oil

Heavy oil seeping out on the surface has been known for a long time and this was easy to exploit for use in small quantities. Even after drilling for oil became successful (in 1857 in Pennsylvania), mining for heavy oil continued in many parts of the world including Germany. In southern California (Ventura and Los Angeles basins) oil was mined from the early 1860s to the 1890s because the heavy oil would not flow to the wells. Tar sands are sandstone reservoirs which have been filled with oil at shallow depth <2 km (<70–80◦C) so that the oil has become biodegraded. Reservoir rocks which have been buried more deeply and then uplifted before the oil migration may be sterilised at higher temperatures and are less likely to be biodegraded. When the sandstone has not been buried to more than about 2 km depth the sand will remain mostly uncemented as loose sand because of a lack of quartz cement. Tar sand contains asphaltic oil rich in asphaltenes and resins. It has a high content of aromatics and naphthenes compared to paraffins, and a high content of nitrogen, sulphur and oxygen (NSO). Most of the hydrocarbon molecules have more that 60 carbon atoms and the boiling point and viscosity are therefore very high. The viscosity of the biodegraded oil is very low and the oil must be heated so that the viscosity is reduced before it can be produced by drilling wells. There are transitions between reservoirs with heavy oil and nearly solid bitumen. Heating can be achieved by soaking the reservoir with injected steam so that the heat of condensation to water helps to heat the oil. This is called cyclic steam injection when the steam is injected in the production well and left to soak for a few weeks before production starts when the oil is warmer. The steam may also be injected in a nearby well and driven towards the production well. Much of the energy is used to heat the water in the reservoir and it is important to reduce the inflow of water from adjacent rocks. One method includes freezing the ground at a distance from the well to avoid the flow of water towards the well. It is also possible to burn some of the oil in the subsurface to provide heat to heat the oil. It has also been proposed to heat the oil electrically, possibly powered by a nuclear reactor to reduce the CO2 emissions from burning oil to produce heat.

Albertan Tar sands
The tar sands in Alberta, Canada (Athabasca) are of Middle Cretaceous age (Aptian, 100 million years). The main reservoir rock is the McMurray Formation, a sandstone representing fluvial to tidal environments, and it is important to find thick sequences of sand with few clay layers. The oil was generated from older source rocks during the Laramide folding of the Rocky Mountains to the west and migrated into the Athabasca sands during the late Cretaceous and early Tertiary. Starting in the Eocene (50 million years) the sand was uplifted and most of the overburden eroded. The oil was then biodegraded by bacteria. These tar sands contain 1.7 trillion bbl (270 × 109 m3) of bitumen in-place, comparable in magnitude to the world’s total proven reserves of conventional petroleum. There are currently large mining operations at Athabasca. At surface temperatures, which are low in northern Canada, this tar sand is rather hard because of the high viscosity of the oil. The oil must be separated from the sand using hot water. The oil (tar) is very viscous and may be denser than water (API <10). Only about 20% is close enough to the surface to be economically mined and the rest must be heated in place. A cubic metre of oil, mined from the tar sands, needs 2–4.5 m3 of water. Oil may be extracted by steam-assisted gravity drainage (SAGD). Two parallel horizontal wells are drilled so that one is about 5 m below the other. Steam is injected in the shallowest well and the heated, less viscous, oil is drained into the lower well where it is produced. The steam will remain near the top due to its low density but will sink when condensed to water. The shales will reduce the vertical permeability and the drainage, but the heating will cause some fracturing which may allow more vertical flow. This method requires rather thick and homogeneous sand. Steam can also be injected into one well for a few weeks until the oil is heated and then produced from the same well. This is called cyclic steam stimulation (CSS). Large amounts of energy and water are required to produce the steam for this method. If petroleum is burned to produce the heat, high emissions of CO2 will result not only from when the oil is burnt as fuel but also from producing it. The steam may be mixed with solvents (gas) and this may reduce the amount of heat (steam) required. Much of the water used to produce steam can be recovered and used again. For each 3 bbl of oil produced one barrel is burned to produce the steam required for the production. This heavy oil should also be mixed with gas during the refining and a supply of gas is therefore important. Heating the oil with electricity has also been proposed and hydroelectric or nuclear power would reduce the CO2 emissions. 173 billion bbl (27.5×109 m3) of crude bitumen, which is 10% of the total bitumen in place, are economically recoverable using current technology from the three Alberta oil sand areas based on benchmark WTI market prices of $62/bbl in 2006, rising to a projected $69/bbl in 2016. The environmental problems associated with oil production from tar sand are considerable and very large amounts of water are required both for the production of steam for subsurface operations and for the processing of loose sand excavated from surface pits. As a result the release of CO2 is higher than with normal petroleum production if the CO2 is not captured and sequestrated. In Venezuela there are also very large reserves of heavy oil and tar sand such as the Orinoco tar sand. While the average surface temperature in Northern Alberta is only slightly above 0◦C the surface temperature in Venezuela is much higher (>20◦C) and the oil therefore needs less heating to reduce its viscosity. Much of the oil in Venezuela is heavy oil and it occurs in a foreland basin in front of the Cordilleran Mountains in a similar plate tectonic position to the heavy oil in Alberta. Also the oil in the Middle East is located in a similar foreland basin but here the reservoir shave not been uplifted so close to the surface and are therefore in most cases not so biodegraded. It is possible to make an emulsion between bitumen and water which has low viscosity and which can flow in pipelines and be burned directly to produce electric power. The heavy oil and bitumen is rather rich in sulphur which should be removed to avoid pollution. It can also be mixed with gas so that it can be used to produce normal oil products. There are other important tar sand deposits in the USA (Utah) and Africa (Congo and Madagascar). Tar sand has only recently been included in data on world oil reserves and as a result Canada has become one of the nations with the highest oil reserves.

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